Luis Suarez has now scored against every La Liga side he has faced since he signed for Barcelona. The Uruguayan hit the fifth in the 5-1 win over Real Valladolid on Tuesday night.
The forward had seen a goal disallowed for offside before Leo Messi set him up to strike in the 77th minute.
The Pistolero has been lethal in La Liga, netting against 27 teams since joining in 2014.
This is his sixth league goal of the season, one below the top scorers Gerard Moreno (Villarreal) and Loren Moron (Betis).
Suarez's Liga victims: Eibar y Betis (10 goals); Real Madrid (9); Deportivo (8); Valencia, Espanyol, Sporting (7); Sevilla, Levante, Las Palmas, Rayo Vallecano (6), Athletic, Getafe, Granada (5); Atlético, Real Sociedad, Villlarreal, Celta, Leganés, Girona, Córdoba (4); Alavés (3); Almería, Huesca (2); Osasuna, Málaga, Valladolid (1).
Suarez has 135 goals in 171 Liga games.